Find the file Mathematica\(version)\SystemFiles\FrontEnd\TextResources\Windows\KeyEventTranslations.tr and back it up before making any modifications. Find the line EventTranslations[{ and add the following two lines right after it:
Item[KeyEvent["[", Modifiers -> {Control}],Now restart the front end and you should be able to type these characters using CTRL-[ and CTRL-]! This has been tested with Mathematica 5.2 and 6.0 on Windows.
FrontEndExecute[{FrontEnd`NotebookWrite[FrontEnd`InputNotebook[],
"\[LeftDoubleBracket]", After]}]],
Item[KeyEvent["]", Modifiers -> {Control}],
FrontEndExecute[{FrontEnd`NotebookWrite[FrontEnd`InputNotebook[],
"\[RightDoubleBracket]", After]}]],
Note: If you keep the backup of KeyEventTranslations.tr in the same directory, make sure that its extension is NOT .tr, otherwise this trick will not work.